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Thiophenol(CAS#108-98-5)

Chemical Property:

Molecular Formula C6H6S
Molar Mass 110.18
Density 1.078
Melting Point -15 °C
Boling Point 169°C(lit.)
Flash Point 123°F
JECFA Number 525
Water Solubility insoluble
Solubility DMSO, Ethyl Acetate
Vapor Presure 1.4 mm Hg ( 20 °C)
Vapor Density 3.8 (vs air)
Appearance Liquid
Color Clear colorless to slightly yellow
Odor Unpleasant
Exposure Limit TLV-TWA 0.5 ppm (~2.5 mg/m3 ) (ACGIH).
Merck 14,9355
BRN 506523
pKa 6.6(at 25℃)
Storage Condition Store at RT.
Stability Stable. Flammable. May form explosive mixtures with air. Stench. Incompatible with strong oxidizing agents.
Sensitive Stench
Refractive Index n20/D 1.588(lit.)
Physical and Chemical Properties Colorless to water-white or light yellow flowable liquid. Has an unpleasant diffuse garlic-like odor. Boiling point 169 °c, or 46.4 °c (1333Pa). Insoluble in water, slightly soluble in ethanol and ether, soluble in oil. Natural products are found in boiled beef.
Use Used as a pharmaceutical Intermediate

Product Detail

Product Tags

Risk Codes R10 – Flammable
R24/25 -
R26 – Very Toxic by inhalation
R41 – Risk of serious damage to eyes
R36/37/38 – Irritating to eyes, respiratory system and skin.
Safety Description S23 – Do not breathe vapour.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 – After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S28A -
S16 – Keep away from sources of ignition.
UN IDs UN 2337 6.1/PG 1
WGK Germany 3
RTECS DC0525000
FLUKA BRAND F CODES 10-13-23
TSCA Yes
HS Code 29309099
Hazard Note Toxic/Stench
Hazard Class 6.1
Packing Group I

 

Introduction

Phenophenol, also known as benzene sulfide, is a colorless to light yellow liquid. The following is an introduction to the properties, uses, preparation methods and safety information of phenol:

 

Quality:

- Appearance: Phenophenol is a colorless to light yellow liquid with a peculiar thiophenol smell.

- Solubility: Phenophenol is insoluble in water, but soluble in many organic solvents such as alcohols, ethers, alcohol ethers, etc.

- Reactivity: Phenophenol is electrophilic and can undergo acid-base neutralization, oxidation, and substitution.

 

Use:

- Chemical industry: Phenophenol can be used as an intermediate in the production of dyes, plastics, and rubber.

- Preservatives: Phenol has certain antibacterial, mold inhibition and antiseptic functions, and is widely used in wood protection, paints, adhesives and other fields.

 

Method:

Phenol can be prepared by the reaction of benzenesulfonyl chloride with sodium hydrosulfide. In the reaction, benzenesulfonyl chloride reacts with sodium hydrogen sulfide to form benzene mercaptan, which is then oxidized to obtain phenylthiophenol.

 

Safety Information:

- Phenophenol is irritating and may cause inflammation in contact with the skin or eyes. Direct contact with skin and eyes should be avoided when using thiophenol, and protective gloves and goggles should be worn if necessary.

- Phenophenol is toxic to the environment and should be avoided for large-scale leakage and discharge into water sources or soil.

- Phenophenol is volatile and may cause symptoms such as dizziness and nausea if exposed to it in an unventilated environment for a long time. A well-ventilated working environment should be maintained when using phenothiophenol.


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