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Tetrahydrofuran(CAS#109-99-9)

Chemical Property:

Molecular Formula C4H8O
Molar Mass 72.11
Density 0.887 g/mL at 20 °C
Melting Point -108°C
Boling Point 66 °C
Flash Point 6 °F (-14 ℃)
Water Solubility miscible
Solubility water: soluble
Vapor Presure <0.01 mm Hg ( 25 °C)
Vapor Density 2.5 (vs air)
Appearance Liquid
Specific Gravity 0.89
Color <10(APHA)
Odor Ethereal, detectable at 2 to 50 ppm
Exposure Limit TLV-TWA 200 ppm (590 mg/m3) (ACGIH,MSHA, and OSHA); STEL 250 ppm(ACGIH); IDLH 20,000 ppm (NIOSH).
Maximum wavelength(λmax) ['λ: 245 nm Amax: ≤0.26',
, 'λ: 275 nm Amax: ≤0.046',
, 'λ: 315 μm Amax: ≤0.0044']
Merck 14,9211
BRN 102391
PH 7-8 (200g/l, H2O, 20℃)
Storage Condition Store at +5°C to +30°C.
Stability Stable. Incompatible with halogens, strong oxidizing agents, strong reducing agents, strong bases, oxygen. May generate explosive peroxides in storage if in contact with air. Highly flammable.
Sensitive Air Sensitive & Hygroscopic
Explosive Limit 1.5-12.4%(V)
Refractive Index n20/D 1.465
Physical and Chemical Properties Characteristics of colorless transparent liquid, ether odor.
boiling point 67 ℃
freezing point -108 ℃
relative density 0.985
refractive index 1.4050
flash point -17 ℃
solubility, ketone, benzene, Ester, ether, hydrocarbon miscible.
Use Used as solvent, raw material of organic synthesis

Product Detail

Product Tags

Risk Codes R36/37/38 – Irritating to eyes, respiratory system and skin.
R36/37 – Irritating to eyes and respiratory system.
R19 – May form explosive peroxides
R11 – Highly Flammable
R40 – Limited evidence of a carcinogenic effect
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 – Wear suitable protective clothing.
S33 – Take precautionary measures against static discharges.
S29 – Do not empty into drains.
S16 – Keep away from sources of ignition.
S46 – If swallowed, seek medical advice immediately and show this container or label.
S37 – Wear suitable gloves.
S13 – Keep away from food, drink and animal foodstuffs.
UN IDs UN 2924 3/PG 2
WGK Germany 1
RTECS MD0916000
FLUKA BRAND F CODES 3-10-23
TSCA Yes
HS Code 29321100
Hazard Class 3
Packing Group II
Toxicity LD50 oral (rat) 2880 mg/kg
LC50 inhal (rat) 21,000 ppm (3 h)
PEL (OSHA) 200 ppm (590 mg/m3)
TLV-TWA (ACGIH) 200 ppm (590 mg/m3)
STEL (ACGIH) 250 ppm (737 mg/m3)

 

Introduction

Quality:1. Tetrahydrofuran is a colorless, flammable liquid with a special odor.2. Tetrahydrofuran can react with many organic compounds, and has a certain solubility, and is often used as an organic solvent.Use:1. Tetrahydrofuran has a wide range of applications in biochemistry and organic synthesis.2. It can be used as a stabilizer for solvents, intermediates and catalysts.3. It is also often used as a reaction medium for polymerization reactions.Method:There are several main methods for the preparation of tetrahydrofuran. One is obtained by hydrogenated furans, which is usually carried out in the presence of hydrogen and under the action of a catalyst. Another method is obtained by reacting propylene oxide with ammonia.Safety Information:1. Tetrahydrofuran has certain toxicity and corrosiveness, so direct contact with skin and eyes should be avoided.2. Wear appropriate protective gloves, goggles and protective clothing during use.3. Tetrahydrofuran is flammable, should be kept away from open flames and heat sources, and stored in a cool and ventilated place.4. When disposing of waste, it should be disposed of in accordance with relevant regulations to reduce the impact on the environment.


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