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Tetraethyl orthosilicate(CAS#78-10-4)

Chemical Property:

Molecular Formula C8H20O4Si
Molar Mass 208.33
Density 0.933 g/mL at 20 °C(lit.)
Melting Point -77 °C
Boling Point 168°C(lit.)
Flash Point 116°F
Water Solubility Hydrolysis
Solubility Soluble in ethanol and 2-propanol.
Vapor Presure <1 mm Hg ( 20 °C)
Vapor Density 7.2 (vs air)
Appearance Liquid
Specific Gravity 0.934
Color Colorless
Exposure Limit ACGIH: TWA 10 ppmOSHA: TWA 100 ppm(850 mg/m3)NIOSH: IDLH 700 ppm; TWA 10 ppm(85 mg/m3)
Merck 14,3851
BRN 1422225
Storage Condition Store below +30°C.
Stability Stable. Flammable. Incompatible with strong oxidizing agents, water, alkalies, mineral acids.
Sensitive Moisture Sensitive
Explosive Limit 1.3-23%(V)
Refractive Index n20/D 1.382(lit.)
Physical and Chemical Properties Colorless flammable liquid with pungent odor.
melting point 110 ℃
boiling point 168.1 ℃
freezing point -77 ℃
relative density 0.9356
flash point 51.67 ℃
solubility insoluble in water, soluble in ethanol, benzene-soluble.
Use Mainly used in optical glass, chemical resistant coatings and heat resistant coatings and adhesives; Anti-corrosion coating modification; Crosslinking agent, binder, dehydrating agent; Catalyst skeleton, high purity ultrafine silica manufacturing.

Product Detail

Product Tags

Hazard Symbols Xn – Harmful
Risk Codes R10 – Flammable
R20 – Harmful by inhalation
R36/37 – Irritating to eyes and respiratory system.
R36/37/38 – Irritating to eyes, respiratory system and skin.
Safety Description S16 – Keep away from sources of ignition.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25 – Avoid contact with skin and eyes.
UN IDs UN 1292 3/PG 3
WGK Germany 1
RTECS VV9450000
TSCA Yes
HS Code 2920 90 70
Hazard Class 3
Packing Group III
Toxicity LD50 orally in Rabbit: 6270 mg/kg LD50 dermal Rabbit 5860 mg/kg

 

Introduction

Ethyl silicate is also known as tetraethyl silicate and tetraethoxysilane. Colorless transparent liquid with special odor. It is stable in the presence of no water, decomposes into ethanol and silicic acid in water, becomes turbid in humid air, and is soluble in organic solvents such as alcohol and ether. Toxic, strong irritation to human eyes and respiratory tract. It is prepared by distillation after the action of silicon tetrachloride and absolute ethanol. It is used to make heat-resistant and chemical-resistant coatings and silicone solvents. It can also be used for organic synthesis, basic raw materials for preparing advanced crystals, optical glass treatment agents, binders, insulating materials for the electronic industry, etc.


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