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Salicylaldehyde(CAS#90-02-8)

Chemical Property:

Molecular Formula C7H6O2
Molar Mass 122.12
Density 1.146 g/mL at 25 °C (lit.)
Melting Point 1-2 °C (lit.)
Boling Point 197 °C (lit.)
Flash Point 170°F
JECFA Number 897
Water Solubility slightly soluble
Solubility 4.9g/l
Vapor Presure 1 mm Hg ( 33 °C)
Vapor Density 4.2 (vs air)
Appearance Liquid
Color Clear yellow
Odor Bitter almonds
Exposure Limit ACGIH: TWA 5 ppm (Skin)OSHA: TWA 5 ppm(19 mg/m3)NIOSH: IDLH 250 ppm; TWA 5 ppm(19 mg/m3); Ceiling 15.6 ppm(60 mg/m3)
Merck 14,8326
BRN 471388
pKa 8.37(at 25℃)
PH 6-8 (H2O, 20℃)Not applicable
Storage Condition -20°C
Stability Stable. Combustible. Incompatible with strong bases, strong reducing agents, strong acids, strong oxidizing agents.
Sensitive Air & Light Sensitive
Refractive Index n20/D 1.573(lit.)
Physical and Chemical Properties Colorless, clear, oily liquid, with scorching odor and almond odor; Vapor pressure:.13kPa/33 ℃; Flash point: 76 ℃; Melting point -7 ℃; Boiling point 197 ℃; Solubility slightly soluble in water, soluble in ethanol, ether; Density: Relative density (water = 1)1.17; stability: Stable
Use Main uses: used as analytical reagents, spices, gasoline additives and for organic synthesis

Product Detail

Product Tags

Risk Codes R21/22 – Harmful in contact with skin and if swallowed.
R36/38 – Irritating to eyes and skin.
R68 – Possible risk of irreversible effects
R36/37/38 – Irritating to eyes, respiratory system and skin.
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
R51 – Toxic to aquatic organisms
R36 – Irritating to the eyes
R51/53 – Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R22 – Harmful if swallowed
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 – Wear suitable protective clothing and gloves.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S36 – Wear suitable protective clothing.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S64 -
S29/35 -
UN IDs 3082
WGK Germany 2
RTECS VN5250000
FLUKA BRAND F CODES 8-10-23
TSCA Yes
HS Code 29122990
Hazard Class 6.1(b)
Packing Group II
Toxicity MLD in rats (mg/kg): 900-1000 s.c. (Binet)

 

Introduction

Salicylaldehyde is an organic compound. The following is an introduction to the properties, uses, preparation methods and safety information of salicylaldehyde:

 

Quality:

- Appearance: Salicylaldehyde is a colorless to yellowish liquid with a special bitter almond aroma.

- Solubility: Salicylaldehyde has a high solubility in water and is also soluble in most organic solvents.

 

Use:

- Flavors and flavors: Salicylaldehyde has a unique bitter almond aroma and is commonly used in perfumes, soaps and tobacco as one of the components of fragrance.

 

Method:

- In general, salicylaldehyde can be produced from salicylic acid through redox reactions. The most commonly used oxidant is acidic potassium permanganate solution.

- Another preparation method is to obtain salicylyl alcohol ester by chlorination ester of phenol and chloroform catalyzed by hydrochloric acid, and then to obtain salicylaldehyde by hydrolysis reaction catalyzed by acid.

 

Safety Information:

- Salicylaldehyde is a harsh chemical and should be avoided from direct contact with the skin and eyes.

- When using or handling salicylaldehyde, maintain good ventilation conditions and avoid inhalation of its vapors.

- When storing salicylaldehyde, it should be kept in an airtight container, away from ignition and oxidants.

- If salicylaldehyde is ingested or inhaled by mistake, seek medical assistance immediately.


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