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N-Phenyl-bis(trifluoromethanesulfonimide)(CAS# 37595-74-7)

Chemical Property:

Molecular Formula C8H5F6NO4S2
Molar Mass 357.25
Density 1.766±0.06 g/cm3(Predicted)
Melting Point 100-102°C(lit.)
Boling Point 305.3±52.0 °C(Predicted)
Flash Point 138.442°C
Solubility Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
Vapor Presure 0.001mmHg at 25°C
Appearance White to off-white crystal
Color White or colorless
BRN 1269141
pKa -13.12±0.50(Predicted)
Storage Condition Keep in dark place,Sealed in dry,Room Temperature
Stability Moisture Sensitive
Sensitive Moisture Sensitive
Refractive Index 1.488
MDL MFCD00000404
Use Trifluoromethyl sulfonylation (Triflating) reagent.

Product Detail

Product Tags

Hazard Symbols Xi – Irritant
Risk Codes 36/37/38 – Irritating to eyes, respiratory system and skin.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 – Wear suitable protective clothing.
WGK Germany 3
FLUKA BRAND F CODES 21
TSCA No
HS Code 29242100
Hazard Class IRRITANT

 

Introduction

N-Phenylbis(trifluoromethanesulfonimide) is an organic compound. It is a white crystalline solid that is soluble in organic solvents such as ether and methylene chloride.

 

N-Phenylbis(trifluoromethanesulfonimide) is commonly used as a reagent and catalyst in organic synthesis. It can react with lithium salts to form corresponding complexes, which are commonly used in organic synthesis to catalyze carbon-carbon coupling reactions, such as Suzuki reaction and Stille reaction. It can also be used in the synthesis of novel organic fluorescent dyes.

 

A common method for the preparation of N-phenylbis(trifluoromethanesulfonimide) is to react N-aniline with fluoride trifluoromethanesulfonate to generate N-phenyl-4-aminotrifluoromethanesulfonate, which is then reacted with hydrofluoric acid to obtain the target product. This method is simple and efficient, and the yield is high.

 

Safety Information: N-Phenylbis(trifluoromethanesulfonimide) may be irritating to the eyes, skin, and respiratory system. Protective eyewear, gloves and respiratory protective equipment should be worn when using. Avoid inhalation or contact with the skin. Maintain good ventilation conditions during handling and storage.


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