Lithium fluoride(CAS#7789-24-4)
| Hazard Symbols | T – Toxic |
| Risk Codes | R25 – Toxic if swallowed R32 – Contact with acids liberates very toxic gas R36/37/38 – Irritating to eyes, respiratory system and skin. R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S22 – Do not breathe dust. S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 3288 6.1/PG 3 |
| WGK Germany | 2 |
| RTECS | OJ6125000 |
| FLUKA BRAND F CODES | 10-21 |
| TSCA | Yes |
| HS Code | 28261900 |
| Hazard Note | Toxic |
| Hazard Class | 6.1 |
| Packing Group | III |
| Toxicity | LD in guinea pigs (mg/kg): 200 orally, 2000 s.c. (Waldbott) |
Introduction
The following is an introduction to the properties, uses, preparation methods and safety information of lithium fluoride:
Quality:
1. Lithium fluoride is a white crystalline solid, odorless and tasteless.
3. Slightly soluble in water, but soluble in alcohols, acids and bases.
4. It belongs to ionic crystals, and its crystal structure is body-centered cube.
Use:
1. Lithium fluoride is widely used as a flux for metals such as aluminum, magnesium, and iron.
2. In the nuclear and aerospace sectors, lithium fluoride is used as a material for the manufacture of reactor fuel and turbine blades for turbine engines.
3. Lithium fluoride has a high melting temperature, and it is also used as a flux in glass and ceramics.
4. In the field of batteries, lithium fluoride is an important raw material for the manufacture of lithium-ion batteries.
Method:
Lithium fluoride is usually prepared by the following two methods:
1. Hydrofluoric acid method: hydrofluoric acid and lithium hydroxide are reacted to generate lithium fluoride and water.
2. Hydrogen fluoride method: hydrogen fluoride is passed into lithium hydroxide solution to generate lithium fluoride and water.
Safety Information:
1. Lithium fluoride is a corrosive substance that has an irritating effect on the skin and eyes, and should be avoided during use.
2. When handling lithium fluoride, appropriate protective gloves and goggles should be worn to prevent accidental contact.
3. Lithium fluoride should be kept away from ignition sources and oxidants to avoid fire or explosion.
