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Heptane(CAS#142-82-5)

Chemical Property:

Molecular Formula C7H16
Molar Mass 100.202
Density 0.695g/cm3
Melting Point -91℃
Boling Point 98.8°C at 760 mmHg
Flash Point 30 °F
Water Solubility practically insoluble
Solubility acetone: miscible(lit.)
Vapor Presure 45.2mmHg at 25°C
Appearance Liquid
Specific Gravity 0.684 (20/4℃)
Color ≤10(APHA)
Odor Gasoline.
Exposure Limit NIOSH REL: TWA 85 ppm (350 mg/m3), 15-min ceiling 440 ppm (1,800 mg/m3), IDLH 750 ppm; OSHA PEL: TWA 500 ppm (2,000 mg/m3); ACGIH TLV: TWA 400 ppm, STEL 500 ppm (adopted).
Maximum wavelength(λmax) λ: 200 nm Amax: ≤1.0
λ: 225 nm Amax: ≤0.10
λ: 250 nm Amax: ≤0.01
λ: 300-400 nm Amax: ≤0.
Merck 14,4659
BRN 1730763
pKa >14 (Schwarzenbach et al., 1993)
Storage Condition Store at +5°C to +30°C.
Stability Stable. Incompatible with oxidizing agents, chlorine, phosphorus. Highly flammable. Readily forms explosive mixtures with air.
Explosive Limit 1-7%(V)
Refractive Index 1.394
Physical and Chemical Properties
appearance colorless volatile liquid
relative vapor density (Air = 1):3.45
saturated vapor pressure (KPa):5.33(22.3 ℃)
combustion heat (kj/mol):4806.6
critical temperature (℃) 201.7
critical pressure (MPa):1.62
ignition temperature (℃) 204
Upper Explosive limit%(V/V):6.7
lower explosive limit%(V/V):1.1
Use Mainly used as a standard for the determination of octane number, but also can be used as anesthetics, solvents and raw materials for organic synthesis, the preparation of experimental reagents

Product Detail

Product Tags

Hazard Symbols F – FlammableXn – HarmfulN – Dangerous for the environment
Risk Codes R11 – Highly Flammable
R38 – Irritating to the skin
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 – Harmful: May cause lung damage if swallowed
R67 – Vapors may cause drowsiness and dizziness
Safety Description S16 – Keep away from sources of ignition.
S29 – Do not empty into drains.
S33 – Take precautionary measures against static discharges.
S60 – This material and its container must be disposed of as hazardous waste.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S62 – If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S9 – Keep container in a well-ventilated place.
UN IDs UN 1206
WGK Germany 3
RTECS MI7700000
FLUKA BRAND F CODES 3-10
TSCA Yes
HS Code 29011000
Hazard Class 3
Packing Group II
Toxicity LC (2 hr in air) in mice: 75 mg/l (Lazarew)

 

Heptane(CAS#142-82-5)

quality
Colorless volatile liquid. Insoluble in water, soluble in alcohol, miscible in ether, chloroform. Its vapor forms an explosive mixture with air, which causes combustion and explosion in case of open flame and high heat energy. It can react strongly with oxidants.

Method
The industrial-grade n-heptane can be purified by concentrated sulfuric acid washing, methanol azeotropic distillation and other methods.

use
It is used as an analytical reagent, a gasoline engine knock test standard, a reference substance for chromatographic analysis, and a solvent. It is used as a standard for the determination of octane number, and can also be used as an intoxicant, solvent and raw material for organic synthesis.

security
mouse intravenous injection LD50: 222mg/kg; mouse inhaled 2h LCso: 75000mg/m3. The substance is harmful to the environment, can cause pollution to water bodies and the atmosphere, and bioaccumulates in important food chains for humans, especially in fish. Heptane can cause dizziness, nausea, anorexia, a staggering gait, and even loss of consciousness and stupor. Store in a cool, ventilated warehouse. Extremely susceptible to fire. Keep away from fire and heat sources. The warehouse temperature should not exceed 30°C. Protect from direct sunlight. Keep the container tightly sealed. It should be stored separately from the oxidizing agent.

 


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