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Formic acid(CAS#64-18-6)

Chemical Property:

Molecular Formula CH2O2
Molar Mass 46.03
Density 1.22 g/mL at 25 °C (lit.)
Melting Point 8.2-8.4 °C (lit.)
Boling Point 100-101 °C (lit.)
Flash Point 133°F
JECFA Number 79
Water Solubility MISCIBLE
Solubility H2O: soluble1g/10 mL, clear, colorless
Vapor Presure 52 mm Hg ( 37 °C)
Vapor Density 1.03 (vs air)
Appearance Liquid
Specific Gravity 1.216 (20℃/20℃)
Color APHA: ≤15
Exposure Limit TLV-TWA 5 ppm (~9 mg/m3) (ACGIH,MSHA, OSHA, and NIOSH); IDLH 100ppm (180 mg/m3) (NIOSH).
Maximum wavelength(λmax) ['λ: 260 nm Amax: 0.03',
, 'λ: 280 nm Amax: 0.01']
Merck 14,4241
BRN 1209246
pKa 3.75(at 20℃)
PH 3.47(1 mM solution);2.91(10 mM solution);2.38(100 mM solution);
Storage Condition 2-8°C
Stability Stable. Substances to be avoided include strong bases, strong oxidizing agents and powdered metals, furfuryl alcohol. Combustible. Hygroscopic. Pressure may build up in tightly closed bottles,、
Sensitive Hygroscopic
Explosive Limit 12-38%(V)
Refractive Index n20/D 1.377
Physical and Chemical Properties Characteristics of Colorless fuming flammable liquid, with a strong pungent odor.melting point 8.4 ℃

boiling point 100.7 ℃

relative density 1.220

refractive index 1.3714

flash point 69 ℃

solubility: soluble in water, ethanol and ether, slightly soluble in benzene.

Use For the preparation of formate, formate, formamide, etc., but also in medicine, printing and dyeing, dyes, leather and other industries have a certain use

Product Detail

Product Tags

Risk Codes R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R34 – Causes burns
R40 – Limited evidence of a carcinogenic effect
R43 – May cause sensitization by skin contact
R35 – Causes severe burns
R36/38 – Irritating to eyes and skin.
R10 – Flammable
Safety Description S36/37 – Wear suitable protective clothing and gloves.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S23 – Do not breathe vapour.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
UN IDs UN 1198 3/PG 3
WGK Germany 2
RTECS LP8925000
FLUKA BRAND F CODES 10
TSCA Yes
HS Code 29151100
Hazard Class 8
Packing Group II
Toxicity LD50 in mice (mg/kg): 1100 orally; 145 i.v. (Malorny)

 

Introduction

formic acid) is a colorless liquid with a pungent odor. The following are the main properties of formic acid:

 

Physical properties: Formic acid is highly soluble and soluble in water and most organic solvents.

 

Chemical properties: Formic acid is a reducing agent that is easily oxidized to carbon dioxide and water. The compound reacts with a strong base to produce formate.

 

The main uses of formic acid are as follows:

 

As a disinfectant and preservative, formic acid can be used in the preparation of dyes and leather.

 

Formic acid can also be used as an ice melting agent and mite killer.

 

There are two main ways to prepare formic acid:

 

Traditional method: Distillation method to produce formic acid by partial oxidation of wood.

 

Modern method: formic acid is prepared by methanol oxidation.

 

Precautions for the safe use of formic acid are as follows:

 

Formic acid has a pungent odor and corrosive properties, so you should wear protective gloves and glasses when using it.

 

Avoid inhaling formic acid vapor or dust, and ensure good ventilation when using.

 

Formic acid can cause combustion and should be stored away from fire and flammable materials.

 


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