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Ethyl acrylate(CAS#140-88-5)

Chemical Property:

Molecular Formula C5H8O2
Molar Mass 100.12
Density 0.921g/mLat 20°C
Melting Point −71°C(lit.)
Boling Point 99°C(lit.)
Flash Point 60°F
JECFA Number 1351
Water Solubility 1.5 g/100 mL (25 ºC)
Solubility 20g/l
Vapor Presure 31 mm Hg ( 20 °C)
Vapor Density 3.5 (vs air)
Appearance Liquid
Color Clear
Odor Characteristic acrylic odor; sharp, fragrant; acrid; slightly nauseating; sharp, ester type.
Exposure Limit TLV-TWA 5 ppm (~20 mg/m3) (ACGIH),25 ppm (~100 mg/m3 (MSHA, NIOSH),TWA skin 25 ppm (100 mg/m3) (OSHA);IDLH 2000 ppm (NIOSH).
Merck 14,3759
BRN 773866
Storage Condition 2-8°C
Stability Stable, but may polymerize upon exposure to light. Highly flammable. Keep cool. Incompatible with oxidizing agents, peroxides and other polymerization initiators.
Explosive Limit 1.8-14%(V)
Refractive Index n20/D 1.406(lit.)
Physical and Chemical Properties Melting point of colorless liquid, volatile.
boiling point <-72 ℃
freezing point 99.8 ℃
relative density 0.9234
refractive index 1.4057
flash point 15 ℃
solubility slightly soluble in water 1.5g/100 mL (25°C) miscible with ethanol and ether, soluble in chloroform.
Use Mainly used for synthetic resin raw materials, and used in coating, textile, leather and other industries

Product Detail

Product Tags

Risk Codes R11 – Highly Flammable
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 – Irritating to eyes, respiratory system and skin.
R43 – May cause sensitization by skin contact
Safety Description S9 – Keep container in a well-ventilated place.
S16 – Keep away from sources of ignition.
S33 – Take precautionary measures against static discharges.
S36/37 – Wear suitable protective clothing and gloves.
UN IDs UN 1917 3/PG 2
WGK Germany 2
RTECS AT0700000
FLUKA BRAND F CODES 8
TSCA Yes
HS Code 2916 12 00
Hazard Class 3
Packing Group II
Toxicity LD50 orally in Rabbit: 550 mg/kg LD50 dermal Rabbit 1800 mg/kg

 

Introduction

Ethyl allylenate. The following is an introduction to the properties, uses, preparation methods and safety information of ethyl allylate:

 

Quality:

- Ethyl allyl proponate is a liquid with a pungent odor, soluble in a variety of organic solvents such as alcohols, ethers, etc., but insoluble in water.

- Ethyl allyl proponate has good stability, but polymerization occurs in sunlight.

 

Use:

- Ethyl allyl propionate is an important intermediate in organic synthesis, which can be used in the production of chemical products such as spices, plastics, and dyes.

- It can also be used as a solvent in industrial fields such as coatings, inks, glues, etc.

- Ethyl allyl can also be used in the preparation of resins, lubricants and plasticizers.

 

Method:

- Ethyl allyl is usually formed by the reaction of ethylene with acrylic acid, which is then anhydrated to ethyl allylate.

- In industry, catalysts such as sulfuric acid are often used to facilitate the reaction.

 

Safety Information:

- Ethyl allyl is a flammable liquid and should be avoided from contact with open flames, high temperatures, and oxidizing agents.

- Wear appropriate personal protective equipment such as gloves, goggles, and protective clothing when in use.

- Avoid contact with the skin, eyes and respiratory tract of ethyl allylenate, rinse immediately with plenty of water and seek medical attention if it does.

- Good ventilation conditions should be taken when storing and using ethyl allylenate.

- When disposing of waste, follow local environmental regulations.


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