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Ethanethiol(CAS#75-08-1)

Chemical Property:

Molecular Formula C2H6S
Molar Mass 62.13
Density 0.839g/mLat 25°C(lit.)
Melting Point -148 °C
Boling Point 35°C(lit.)
Flash Point 1°F
JECFA Number 1659
Water Solubility Soluble in alcohol, ether, waterMiscible with alcohol, petroleum naphtha, acetone, dilute alkali and ether. Slightly miscible with water.
Solubility 6.8g/l
Vapor Presure 8.51 psi ( 20 °C)
Vapor Density 2.1 (vs air)
Appearance Liquid
Color Colorless
Odor Strong chunk; offensive garlic.
Exposure Limit TLV-TWA 0.5 ppm (~1.3 mg/m3 ) (ACGIHand MSHA); ceiling 10 ppm (OSHA); IDLH2500 ppm (NIOSH).
Merck 14,3726
BRN 773638
pKa 10.6(at 25℃)
Storage Condition Store below +30°C.
Stability Stable. Extremely flammable – note low flash point. Incompatible with oxidizing agents, strong acids. May form explosive mixtures with air.
Explosive Limit 2.8-18%(V)
Refractive Index n20/D 1.4306(lit.)
Physical and Chemical Properties Colorless transparent oily liquid with strong persistent pungent garlic odor. Volatile in the air.
melting point -147.89 ℃
boiling point 35 ℃
relative density 0.8391
refractive index 1.4310
soluble in water, 20 ° C in water solubility of 1.5% (weight ratio), soluble in alkaline water and ethanol, ether and other organic solvents.
Use For pesticide intermediates, warning gas

Product Detail

Product Tags

Risk Codes R11 – Highly Flammable
R20 – Harmful by inhalation
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 – Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R12 – Extremely Flammable
R20/22 – Harmful by inhalation and if swallowed.
Safety Description S16 – Keep away from sources of ignition.
S25 – Avoid contact with eyes.
S60 – This material and its container must be disposed of as hazardous waste.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
UN IDs UN 2363 3/PG 1
WGK Germany 3
RTECS KI9625000
FLUKA BRAND F CODES 13
TSCA Yes
HS Code 2930 90 98
Hazard Class 3
Packing Group I
Toxicity LD50 orally in Rabbit: 682 mg/kg

 

Introduction

Ethyl mercaptan. The following is an introduction to the properties, uses, preparation methods and safety information of ethyl mercaptan:Quality:- Appearance: Colorless liquid with a foul-smelling taste.- Density: approx. 0.840 g/cm³.- Solubility: Soluble in water, alcohols, and certain organic solvents.Use:- Chemical synthesis: Ethyl mercaptan can be used as an intermediate in the synthesis of organic compounds, and is often used as a reducing agent, sulfiding agent or stabilizer in organic synthesis reactions.Method:- Industrial production: Ethyl mercaptans are generally obtained by the reaction of sodium hydrosulfide and acetonylated hydrocarbons. The specific reaction conditions and steps are determined according to the actual situation of the reaction system.- Laboratory preparation: Ethyl mercaptan can be obtained by the reaction of ethyl magnesium bromide and hydrogen sulfide.Safety Information:- Ethyl mercaptan has a strong odor and strong irritation, so care should be taken to avoid inhaling its vapors or touching the skin.- Toxic sulfide gases are released when burned, so avoid contact with ignition sources.- Ethyl mercaptan is irritating to the eyes and skin, and direct contact should be avoided during use.- Avoid contact with oxidants and strong acids during storage to prevent dangerous reactions.


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