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Diphenylsilanediol; Diphenyldihydroxysilane(CAS#947-42-2)

Chemical Property:

Molecular Formula C12H12O2Si
Molar Mass 216.31
Density 0.87
Melting Point 144-147°C
Boling Point 353°C [760mmHg]
Flash Point 129°F
Water Solubility reacts
Vapor Presure 0Pa at 25℃
Vapor Density >1 (vs air)
Appearance Powder
Color white
BRN 2523445
pKa 12.06±0.53(Predicted)
Storage Condition Inert atmosphere,Room Temperature
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
Sensitive Air & Light Sensitive
Refractive Index 1.615
Physical and Chemical Properties White needle crystal. Melting point 140-141 ℃ (water loss decomposition).
Use Used as silicone rubber structure control agent, raw material of benzyl silicone oil and intermediate of other silicon products

Product Detail

Product Tags

Hazard Symbols F – Flammable
Risk Codes R11 – Highly Flammable
R10 – Flammable
Safety Description S16 – Keep away from sources of ignition.
S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37 – Wear suitable gloves.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDs UN 1325 4.1/PG 3
WGK Germany 1
RTECS VV3640000
TSCA Yes
HS Code 29319090
Hazard Class 4.1
Packing Group III

 

Introduction

Diphenylsiliconediol (also known as arylsilicondiol or DPhOH) is an organosilicon compound.

 

Common properties of diphenylsilicondiol include:

1. Physical properties: colorless crystalline solid, soluble in organic solvents such as ethanol and dimethylformamide.

2. Chemical properties: It has good electrophilicity and can condense with many compounds such as acid chloride, ketones, esters, etc.

 

The main uses of diphenylsilicondiol include:

1. Organic synthesis: its electrophilicity can be used as a condensation reagent for the generation of esters, ethers, ketones and other target products in organic synthesis.

2. Material chemistry: As an organosilicon intermediate, it can be used to prepare organosilicon polymers and polymers.

3. Surfactant: It can be used as a raw material for surfactant.

 

The preparation method of diphenylsilicondiol is generally obtained by the reaction of phenylsilyl hydrogen (PhSiH3) with water. Transition metal catalysts such as palladium chloride (PdCl2) or platinum chloride (PtCl2) are often used in the reaction.

 

Safety Information: Diphenylsilicondiol is relatively safe and non-toxic under normal use conditions. It is still necessary to follow the safety protocols of general chemical laboratories during operation, such as wearing personal protective equipment, avoiding contact with skin and eyes, and avoiding inhalation or ingestion. For specific safety information and protective measures, the safety data sheet or relevant safety guidelines for the compound should be consulted.


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