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cyclopentadiene(CAS#542-92-7)

Chemical Property:

Molecular Formula C5H6
Molar Mass 66.1
Density d40 0.8235; d410 0.8131; d420 0.8021; d425 0.7966; d430 0.7914
Melting Point -85°; mp 32.5°
Boling Point bp760 41.5-42.0°
Water Solubility 10.3 mM at 25 °C (shake flask-UV spectrophotometry, Streitwieser and Nebenzahl, 1976)
Solubility Miscible with acetone, benzene, carbon tetrachloride, and ether. Soluble in acetic acid, aniline, andcarbon disulfide (Windholz et al., 1983).
Vapor Presure 381 at 20.6 °C, 735 at 40.6 °C, 1,380 at 60.9 °C (Stoeck and Roscher, 1977)
Appearance Colorless liquid
Exposure Limit TLV-TWA 75 ppm (~202 mg/m3) (ACGIH,NIOSH, and OSHA); IDLH 2000 ppm(NIOSH).
pKa 16(at 25℃)
Stability Stable at room temperature. Incompatible with oxidizing agents, acids and a wide variety of other compounds. May form peroxides in storage. May undergo spontaneous polymerisation.Decomposes on heating
Refractive Index nD16 1.44632
Physical and Chemical Properties This product is a colorless liquid, M.P.-97.2 ℃, B. P. 40 ℃,n20D 1.4446, relative density 0.805 (19/4 ℃), miscible with alcohol, ether, benzene and carbon tetrachloride, soluble in carbon disulfide, aniline, acetic acid and liquid paraffin, insoluble in water. The polymerization was carried out at room temperature to produce dicyclopentadiene. cyclopentadiene dimer, M.P. -1 ℃, B. P. 170 ℃,n20D 1.1510, relative density 0.986. Cyclopentadiene is typically present as a dimer.

Product Detail

Product Tags

UN IDs 1993
Hazard Class 3.2
Packing Group III
Toxicity LD50 of dimer orally in rats: 0.82 g/kg (Smyth)

 

Introduction

Cyclopentadiene (C5H8) is a colorless, pungent odor liquid. It is a highly unstable olefin that is highly polymerized and relatively flammable.

 

Cyclopentadiene has a wide range of applications in chemical research. It can also be used as a raw material for polymers and rubbers to improve their physical and chemical properties.

 

There are two main methods for the preparation of cyclopentadiene: one is produced from the cracking of paraffin oil, and the other is prepared by the isomerization reaction or hydrogenation reaction of olefins.

 

Cyclopentadiene is highly volatile and flammable, and is a flammable liquid. In the process of storage and transportation, fire and explosion prevention measures need to be taken to avoid contact with open flames and high temperatures. Wear appropriate protective equipment such as gloves, goggles, and blast clothing when using and handling cyclopentadiene. At the same time, care should be taken to avoid contact with the skin and inhalation of its vapors, so as not to cause irritation and poisoning. In the event of an accidental leak, cut off the source of the leak quickly and clean it up with appropriate absorbent materials. In industrial production, relevant safety operating procedures and measures need to be adhered to to ensure operational safety.


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