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Cyanogen bromide(CAS# 506-68-3)

Chemical Property:

Molecular Formula CBrN
Molar Mass 105.92
Density 1.443g/mLat 25°C
Melting Point 50-53 °C (lit.)
Boling Point 61-62 °C (lit.)
Flash Point 61.4°C
Water Solubility decomposed slowly by cold H2O [HAW93]
Solubility Soluble in chloroform, dichloromethane, ethanol, diethyl ether, benzene and acetonitrile.
Vapor Presure 100 mm Hg ( 22.6 °C)
Vapor Density 3.65 (vs air)
Appearance Solution
Color White
Odor Penetrating odor
Exposure Limit No exposure limit is set. However, on the basis of the exposure limits of related compounds a ceiling limit of 0.5 ppm (2 mg/m3) is recommended.
Merck 14,2693
BRN 1697296
Storage Condition 2-8°C
Stability Stable. Reacts violently with water and with mineral and organic acids.
Sensitive Moisture & Light Sensitive
Refractive Index 1.4670 (estimate)
Use Used as bactericide and military gas, also for the preparation of cyanide, Organic synthesis

Product Detail

Product Tags

Risk Codes R26/27/28 – Very toxic by inhalation, in contact with skin and if swallowed.
R34 – Causes burns
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R40 – Limited evidence of a carcinogenic effect
R11 – Highly Flammable
R36/37 – Irritating to eyes and respiratory system.
R32 – Contact with acids liberates very toxic gas
R51/53 – Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description S53 – Avoid exposure – obtain special instructions before use.
S28 – After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 – This material and its container must be disposed of as hazardous waste.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16 – Keep away from sources of ignition.
S7/9 -
S29 – Do not empty into drains.
S7 – Keep container tightly closed.
UN IDs UN 3390 6.1/PG 1
WGK Germany 3
RTECS GT2100000
FLUKA BRAND F CODES 8-17-19-21
TSCA Yes
HS Code 28530090
Hazard Class 6.1
Packing Group I
Toxicity LCLO inhal (human) 92 ppm (398 mg/m3; 10 min)LCLO inhal (mouse) 115 ppm (500 mg/m3; 10 min)

 

Introduction

Cyanide bromide is an inorganic compound. The following is an introduction to the properties, uses, preparation methods and safety information of cyanide bromide:

 

Quality:

- Cyanide bromide is a colorless liquid with a pungent odor at room temperature.

- It is soluble in water, alcohol, and ether, but insoluble in petroleum ether.

- Cyanide bromide is highly toxic and can cause serious harm to humans.

- It is an unstable compound that gradually decomposes into bromine and cyanide.

 

Use:

- Cyanide bromide is mainly used as a reagent in organic synthesis and is often used in the preparation of organic compounds containing cyano groups.

 

Method:

Cyanide bromide can be prepared by:

- Hydrogen cyanide reacts with bromide: Hydrogen cyanide reacts with bromine catalyzed by silver bromide to produce cyanide bromide.

- Bromine reacts with cyanogen chloride: Bromine reacts with cyanogen chloride under alkaline conditions to form cyanogen bromide.

- Reaction of cyanocyanide chloride with potassium bromide: Cyanuride chloride and potassium bromide react in an alcohol solution to form cyanide bromide.

 

Safety Information:

- Cyanide bromide is highly toxic and can cause harm to humans, including irritation of the eyes, skin and respiratory system.

- Strict precautions must be taken when using or coming into contact with cyanide bromide, including wearing protective eyewear, gloves and respiratory protection.

- Cyanide bromide must be used in a well-ventilated place, away from fire and heat sources.

- Strict safety operating procedures should be followed when handling cyanide bromide and relevant regulations and guidelines should be followed.


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