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Acrolein(CAS#107-02-8)

Chemical Property:

Molecular Formula C3H4O
Molar Mass 56.06
Density 0.839g/mLat 25°C(lit.)
Melting Point −87°C(lit.)
Boling Point 53°C(lit.)
Flash Point −2°F
Water Solubility Soluble. 21.25 g/100 mL
Solubility H2O: soluble2 to 3 parts
Vapor Presure 4.05 psi ( 20 °C)
Vapor Density 1.94 (vs air)
Appearance Liquid
Color Colourless to Pale Yellow
Odor Pungent, lacrimatory, intensely irritating odor detectable at 0.02 to 0.4 ppm
Exposure Limit NIOSH REL: TWA 0.1 ppm, STEL 0.3 ppm, IDLH 2 ppm; OSHAPEL: TWA 0.1 ppm; ACGIH TLV: TWA 0.1 ppm, STEL 0.3 ppm.
Merck 14,128
BRN 741856
Storage Condition 2-8°C
Stability Stable, but very readily polymerizes. May have ca. 0.1% hydroquinone added as stabilizer. Flammable. Incompatible with oxidizing agents, reducing agents, oxygen, a variety of other chemicals, light.
Sensitive Air & Light Sensitive
Explosive Limit 31%
Refractive Index n20/D 1.403(lit.)
Physical and Chemical Properties Colorless transparent flammable volatile unstable liquid, with strong irritation, its vapor has a strong tear. Soluble in 2~3 times of water, soluble in ethanol, ether, acetone.
Use As one of the important raw materials of synthetic resin industry, it is also widely used in organic synthesis and drug synthesis.

Product Detail

Product Tags

Risk Codes R11 – Highly Flammable
R24/25 -
R26 – Very Toxic by inhalation
R34 – Causes burns
R50 – Very Toxic to aquatic organisms
R26/28 – Very toxic by inhalation and if swallowed.
R24 – Toxic in contact with skin
Safety Description S23 – Do not breathe vapour.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 – After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S16 – Keep away from sources of ignition.
UN IDs UN 1092 6.1/PG 1
WGK Germany 3
RTECS AS1050000
FLUKA BRAND F CODES 8-9
TSCA Yes
HS Code 29121900
Hazard Class 6.1
Packing Group I
Toxicity LD50 orally in rats: 0.046 g/kg (Smyth)

 

Introduction

Acrolein. The following is an introduction to the properties, uses, manufacturing methods and safety information of acrolein:Quality:- Acrolein has a strong pungent odor and is soluble in water and a variety of organic solvents.- It is an unstable compound that is susceptible to polymerization reactions.- In air, acrolein slowly polymerizes and forms polymers, which are prone to spontaneous combustion.Use:- Acrolein is widely used in the chemical industry as a starting substance for the synthesis of other compounds.- It can be used to make polymer materials such as resins, rubber, and plastics.- Acrolein can also be used as a reagent in organic synthesis for the synthesis of a variety of organic compounds.Method:- Acrolein can be prepared by the oxidation of acrylenone. Oxidants are commonly used in oxygen, hydrogen peroxide or neutral potassium permanganate solutions.- During the preparation process, it is necessary to control the reaction temperature and the amount of oxidant to avoid the occurrence of side reactions.Safety Information:- Acrolein is irritating and pathogenic, so take care to protect it from contact with skin and eyes.- Avoid inhaling acrolein gases or vapours and keep them well ventilated.- When handling acrolein, wear appropriate protective gloves, goggles, and protective clothing.- Store in an airtight container, away from fire and oxidants.


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