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4,4′-Diphenylmethane diisocyanate(CAS#101-68-8)

Chemical Property:

Molecular Formula C15H10N2O2
Molar Mass 250.25
Density 1.19
Melting Point 38-44 °C
Boling Point 392 °C
Flash Point 196 °C
Water Solubility decomposes
Solubility 2g/l (decomposition)
Vapor Presure 0.066 hPa (20 °C)
Appearance neat
Specific Gravity 1.180
Color White to Almost white
Exposure Limit TLV-TWA 0.051 mg/m3 (0.005 ppm)(ACGIH and NIOSH); ceiling (air) 0.204mg/m3 (0.02 ppm)/10 min (NIOSH andOSHA); IDLH 102 mg/m3 (10 ppm).
BRN 797662
Storage Condition -20°C
Stability Stable. Combustible. Incompatible with strong oxidizing agents. Reacts violently with alcohols.
Sensitive Moisture Sensitive/Lachrymatory
Explosive Limit 0.4%(V)
Refractive Index 1.5906 (estimate)
Physical and Chemical Properties The trait is a pale yellow molten solid with a strong irritating odor.
boiling point 196 ℃
freezing point 37 ℃
relative density 1.1907
soluble in acetone, benzene, kerosene, nitrobenzene.flash point: 200-218

refractive index: 1.5906

Use Used in the plastics and rubber industries and as an adhesive

Product Detail

Product Tags

Risk Codes R42/43 – May cause sensitization by inhalation and skin contact.
R36/37/38 – Irritating to eyes, respiratory system and skin.
R20 – Harmful by inhalation
R48/20 -
R40 – Limited evidence of a carcinogenic effect
Safety Description S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37 – Wear suitable protective clothing and gloves.
S23 – Do not breathe vapour.
UN IDs 2206
WGK Germany 1
RTECS NQ9350000
TSCA Yes
HS Code 29291090
Hazard Note Toxic/Corrosive/Lachrymatory/Moisture Sensitive
Hazard Class 6.1
Packing Group II
Toxicity LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 9000 mg/kg

 

Introduction

Diphenylmethane-4,4′-diisocyanate, also known as MDI. It is an organic compound and is a type of benzodiisocyanate compounds.

 

Quality:

1. Appearance: MDI is colorless or light yellow solid.

2. Solubility: MDI is soluble in organic solvents such as chlorinated hydrocarbons and aromatic hydrocarbons.

 

Use:

It is used as a raw material for polyurethane compounds. It can react with polyether or polyurethane polyols to form polyurethane elastomers or polymers. This material has a wide range of applications in construction, automotive, furniture, and footwear, among others.

 

Method:

The method of diphenylmethane-4,4′-diisocyanate is mainly to react aniline with isocyanate to obtain aniline-based isocyanate, and then go through diazotization reaction and denitrification to obtain the target product.

 

Safety Information:

1. Avoid contact: Avoid direct skin contact and be equipped with appropriate personal protective equipment such as gloves, goggles and protective clothing.

2. Ventilation: Maintain good ventilation conditions during operation.

3. Storage: When storing, it should be sealed and kept away from fire sources, heat sources and places where ignition sources occur.

4. Waste disposal: Waste should be properly treated and disposed of, and should not be dumped at will.

When handling chemical substances, they should be handled in strict accordance with laboratory operating procedures and safety guidelines, and in accordance with relevant laws and regulations.


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