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3-Nitroaniline(CAS#99-09-2)

Chemical Property:

Molecular Formula C6H6N2O2
Molar Mass 138.12
Density 0,901 g/cm3
Melting Point 111-114 °C (lit.)
Boling Point 306 °C
Flash Point 196 °C
Water Solubility 1.25 g/L
Solubility 1.25g/l
Vapor Presure 1 mm Hg ( 119 °C)
Appearance Crystals, Crystalline Powder and/or Chunks
Specific Gravity 0.901
Color Yellow to ochre-yellow to orange
Merck 14,6581
BRN 636962
pKa 2.466(at 25℃)
Storage Condition Store below +30°C.
Refractive Index 1.6396 (estimate)
Physical and Chemical Properties Yellow needle-like crystal or powder.
melting point 114 ℃
boiling point 286~307 ℃ (decomposition)
relative density 1.1747
solubility slightly soluble in water, soluble in ethanol, ether, methanol.
Use Slightly soluble in water, soluble in ethanol, ether, methanol.

Product Detail

Product Tags

Hazard Symbols T – Toxic
Risk Codes R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R33 – Danger of cumulative effects
R52/53 – Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description S28 – After contact with skin, wash immediately with plenty of soap-suds.
S36/37 – Wear suitable protective clothing and gloves.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S28A -
UN IDs UN 1661 6.1/PG 2
WGK Germany 2
RTECS BY6825000
FLUKA BRAND F CODES 8
TSCA Yes
HS Code 29214210
Hazard Class 6.1
Packing Group II
Toxicity Acute LD50 for guinea pigs 450 mg/kg, mice 308 mg/kg, quail 562 mg/kg, rats 535 mg/kg
(quoted, RTECS, 1985).

 

Introduction

M-nitroaniline is an organic compound. It is a yellow crystal with a peculiar foul odor.

 

The main use of m-nitroaniline is as a dye intermediate and as a raw material for explosives. It can prepare other compounds by reacting with certain compounds, such as nitrate compounds can be prepared by reacting with nitric acid, or dinitrobenzoxazole can be prepared by reacting with thionyl chloride.

 

The preparation method of m-nitroaniline can be obtained by the reaction of m-aminophenol with nitric acid. The specific step is to dissolve m-aminophenol in sulfuric acid containing nitric acid and stir the reaction, then cool and crystallize to finally obtain the product of m-nitroaniline.

 

Safety information: M-nitroaniline is a toxic substance that has an irritating effect on the eyes, skin, and respiratory tract. Contact with the skin can cause inflammation and redness, and inhalation of high concentrations of vapor or dust may cause poisoning. Wear protective glasses, gloves, protective clothing, and respirators when operating, and ensure that the operation is carried out in well-ventilated conditions. Any possible contact should be immediately rinsed with plenty of water and immediately treated with medical attention. Moreover, m-nitroaniline is explosive and should be kept away from open flames and high temperatures.


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