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3-Methyl-1-butanol(CAS#123-51-3)

Chemical Property:

Molecular Formula C5H12O
Molar Mass 88.15
Density 0.809g/mLat 25°C(lit.)
Melting Point -117 °C
Boling Point 131-132°C
Flash Point 109.4°F
JECFA Number 52
Water Solubility 25 g/L (20 ºC)
Solubility 25g/l
Vapor Presure 2 mm Hg ( 20 °C)
Vapor Density 3 (vs air)
Appearance Liquid
Specific Gravity 0.813 (15/4℃)
Color <20(APHA)
Odor Mild odor; alcoholic, non-residual.
Exposure Limit NIOSH REL: TWA 100 ppm (360 mg/m3), IDLH 500 ppm; OSHA PEL: TWA100 ppm; ACGIH TLV: TWA 100 ppm, STEL 125 ppm (adopted).
Maximum wavelength(λmax) ['λ: 260 nm Amax: 0.06',
, 'λ: 280 nm Amax: 0.06']
Merck 14,5195
BRN 1718835
pKa >14 (Schwarzenbach et al., 1993)
PH 7 (25g/l, H2O, 20℃)
Storage Condition room temp
Stability Stable. Flammable. Incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides.
Explosive Limit 1.2-9%, 100°F
Refractive Index n20/D 1.407
Physical and Chemical Properties Also known as 3-methyl -1-butanol, isobutyl methanol. Colorless transparent liquid with an unpleasant odor. Melting Point -117.2 °c. Boiling point 130.5 °c. 0.812. 1.4084. Viscosity (24 C) 3.86mPa-s. Flash point (Open Cup) 56 °c. Isoamyl alcohol slightly soluble in water, soluble in alcohol, ether ketone, benzene, chloroform and petroleum ether. An azeotrope can be formed with water with a water content of 49.6% by mass.
Use Used in the manufacture of spices, pharmaceutical and photographic drugs, can also be used as a solvent

Product Detail

Product Tags

Hazard Symbols Xn – Harmful
Risk Codes R10 – Flammable
R20 – Harmful by inhalation
R37 – Irritating to the respiratory system
R66 – Repeated exposure may cause skin dryness or cracking
R20/22 – Harmful by inhalation and if swallowed.
Safety Description S46 – If swallowed, seek medical advice immediately and show this container or label.
S16 – Keep away from sources of ignition.
UN IDs UN 1105 3/PG 3
WGK Germany 1
RTECS EL5425000
TSCA Yes
HS Code 29335995
Hazard Class 3
Packing Group II
Toxicity LD50 orally in rats: 7.07 ml/kg (Smyth)

 

Introduction

Isoamyl alcohol, also known as isobutanol, has the chemical formula C5H12O. The following is an introduction to its nature, use, preparation method and safety information:

 

Quality:

1. Isoamyl alcohol is a colorless liquid with a special wine aroma.

2. It has a boiling point of 131-132 °C and a relative density of 0.809g/mLat 25 °C (lit.).

3. Isoamyl alcohol is soluble in water and most organic solvents.

 

Use:

1. Isoamyl alcohol is often used as a solvent and has a wide range of applications in coatings, inks, adhesives and cleaning agents.

2. Isoamyl alcohol can also be used to synthesize other compounds such as ethers, esters, and aldehydes and ketones.

 

Method:

1. A common preparation method of isoamyl alcohol is obtained by acidic alcohololysis reaction of ethanol and isobutylene.

2. Another preparation method is obtained by hydrogenation of isobutylene.

 

Safety Information:

1. Isoamyl alcohol is a flammable liquid that can cause a fire when exposed to an ignition source.

2. When using isoamyl alcohol, it is necessary to avoid inhalation, contact with the skin or ingestion into the body to prevent damage to health.

3. Good ventilation measures should be taken when using isoamyl alcohol to ensure indoor air circulation.

4. In case of leakage, isoamyl alcohol should be isolated quickly, and the leakage should be properly disposed of to avoid reaction with other substances.


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