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2-Nitroaniline(CAS#88-74-4)

Chemical Property:

Molecular Formula C6H6N2O2
Molar Mass 138.12
Density 1,255 g/cm3
Melting Point 70-73 °C (lit.)
Boling Point 284 °C (lit.)
Flash Point 168 °C
Water Solubility 1.1 g/L (20 ºC)
Solubility methanol: 0.1g/mL, clear
Vapor Presure 8.1 at 25 °C (Mabey et al., 1982)
Appearance Crystals or Flakes
Color Orange to brown
Merck 14,6582
BRN 509275
pKa -0.26(at 25℃)
PH 6.1 (10g/l, H2O, 20℃)(slurry)
Storage Condition Store below +30°C.
Stability Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents, chloroformates, hexanitroethane.
Refractive Index 1.6349 (estimate)
Physical and Chemical Properties Orange-red needle-like crystals.
Use Used as dye intermediates and photographic ash control agent raw materials, can also be used for the production of pesticide carbendazim

Product Detail

Product Tags

Risk Codes R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R33 – Danger of cumulative effects
R52/53 – Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39/23/24/25 -
R11 – Highly Flammable
Safety Description S28 – After contact with skin, wash immediately with plenty of soap-suds.
S36/37 – Wear suitable protective clothing and gloves.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S28A -
S16 – Keep away from sources of ignition.
S7 – Keep container tightly closed.
UN IDs UN 1661 6.1/PG 2
WGK Germany 2
RTECS BY6650000
FLUKA BRAND F CODES 8
TSCA Yes
HS Code 29214210
Hazard Class 6.1
Packing Group II
Toxicity LD50 orally in Rabbit: 1600 mg/kg LD50 dermal Rabbit > 7940 mg/kg

 

Introduction

2-nitroaniline, also known as O-nitroaniline, is an organic compound. The following is an introduction to the properties, uses, preparation methods and safety information of 2-nitroaniline.

 

Quality:

- Appearance: 2-nitroaniline is a yellow crystal or crystalline powder.

- Solubility: 2-nitroaniline is soluble in ethanol, ether and benzene, and slightly soluble in water.

 

Use:

- Production of dyes: 2-nitroaniline can be used in the synthesis of dye intermediates, such as the preparation of aniline yellow dye.

- Explosives: 2-nitroaniline has explosive properties and can be used as a raw material for explosives and pyrotechnics.

 

Method:

- 2-nitroaniline can be prepared by the reaction of aniline with nitric acid. The reaction conditions are generally carried out at low temperatures and sulfuric acid is used as a catalyst.

- Reaction equation: C6H5NH2 + HNO3 -> C6H6N2O2 + H2O

 

Safety Information:

- 2-Nitroaniline is an explosive compound that may be caused by exposure to ignition or high temperatures. It should be kept away from open flames, heat sources, electric sparks, etc.

- Wear protective glasses and gloves when operating to avoid inhaling dust or touching the skin, and avoid accidental ingestion.

- When coming into contact with 2-nitroaniline, rinse immediately with plenty of water and seek medical attention for treatment.

 


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