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1-Butanol(CAS#71-36-3)

Chemical Property:

Molecular Formula C4H10O
Molar Mass 74.12
Density 0.81 g/mL at 25 °C (lit.)
Melting Point -90 °C (lit.)
Boling Point 116-118 °C (lit.)
Flash Point 95°F
JECFA Number 85
Water Solubility 80 g/L (20 ºC)
Solubility Soluble in DMSO
Vapor Presure 6.7 hPa (20 °C)
Vapor Density 2.55 (vs air)
Appearance White powder
Color APHA: ≤10
Odor Alcohol-like; pungent; strong; characteristic; mildly alcoholic, non residual.
Exposure Limit TLV-TWA 300 mg/m3 (100 ppm) (NIOSH),150 mg/m3 (50 ppm) (ACGIH); IDLH 8000ppm (NIOSH).
Maximum wavelength(λmax) λ: 215 nm Amax: 1.00λ: 220 nm Amax: 0.50λ: 240 nm Amax: 0.10λ: 260 nm Amax: 0.04λ: 280-400 nm Amax:
Merck 14,1540
BRN 969148
pKa 15.24±0.10(Predicted)
PH 7 (70g/l, H2O, 20℃)
Storage Condition Store at +5°C to +30°C.
Stability Stable. Incompatible with strong acids, strong oxidizing agents, aluminium, acid chlorides, acid anhydrides, copper, copper alloys. Flammable.
Sensitive Moisture Sensitive
Explosive Limit 1.4-11.3%(V)
Refractive Index n20/D 1.399(lit.)
MDL MFCD00002902
Physical and Chemical Properties Characteristics of colorless liquid, with the taste of alcohol.
melting point -90.2 ℃
boiling point 117.7 ℃
relative density 0.8109
refractive index 1.3993
flash point 35~35.5 ℃
solubility at 20 ℃ solubility in water 7.7% by weight, the solubility of water in n-butanol was 20.1% by weight. Miscible with ethanol, ether and other organic solvents.
Use Used in the production of butyl acetate, dibutyl phthalate and phosphoric acid plasticizer, also used in the production of melamine resin, acrylic acid, epoxy varnish, etc

Product Detail

Product Tags

Risk Codes R10 – Flammable
R22 – Harmful if swallowed
R37/38 – Irritating to respiratory system and skin.
R41 – Risk of serious damage to eyes
R67 – Vapors may cause drowsiness and dizziness
R39/23/24/25 -
R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R11 – Highly Flammable
Safety Description S13 – Keep away from food, drink and animal foodstuffs.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 – Wear suitable gloves and eye/face protection
S46 – If swallowed, seek medical advice immediately and show this container or label.
S7/9 -
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37 – Wear suitable protective clothing and gloves.
S16 – Keep away from sources of ignition.
S7 – Keep container tightly closed.
UN IDs UN 1120 3/PG 3
WGK Germany 1
RTECS EO1400000
TSCA Yes
HS Code 2905 13 00
Hazard Class 3
Packing Group III
Toxicity LD50 orally in rats: 4.36 g/kg (Smyth)

 

Introduction

N-butanol, also known as butanol, is an organic compound, it is a colorless liquid with a peculiar alcoholic odor. The following is an introduction to the properties, uses, preparation methods and safety information of n-butanol:

 

Quality:

1. Physical properties: It is a colorless liquid.

2. Chemical properties: It can be dissolved in water and organic solvents, and is a moderately polar compound. It can be oxidized to butyraldehyde and butyric acid, or it can be dehydrated to form butene.

 

Use:

1. Industrial use: It is an important solvent and has a wide range of applications in the chemical industry such as coatings, inks, and detergents.

2. Laboratory use: It can be used as a solvent to induce helical protein folding, and is often used in biochemical experiments to catalyze reactions.

 

Method:

1. Butylene hydrogenation: After hydrogenation reaction, butene is reacted with hydrogen in the presence of a catalyst (such as a nickel catalyst) to obtain n-butanol.

2. Dehydration reaction: butanol is reacted with strong acids (such as concentrated sulfuric acid) to generate butene through dehydration reaction, and then butene is hydrogenated to obtain n-butanol.

 

Safety Information:

1. It is a flammable liquid, avoid contact with the fire source, and keep away from open flames and high temperature environments.

3. It has a certain toxicity, avoid direct contact with the skin and eyes, and avoid inhaling its vapor.

4. When storing, it should be stored in a closed space, away from oxidants and fire sources, and stored at room temperature.


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